Alkylcobalt(III) compounds with ammine ligands

Pauli Kofod

doi:10.1016/j.inoche.2005.07.014

Alkylcobalt(III) compounds with ammine ligands

Pauli Kofod

Ernæring og Sundhedsuddannelsen - Slagelse

Publikation: Bidrag til tidsskrift › Tidsskriftsartikel › Forskning › peer review

Abstract

Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

Originalsprog	Engelsk
Tidsskrift	Inorganic Chemistry Communications
Vol/bind	8
Udgave nummer	10
Sider (fra-til)	943-946
Antal sider	4
ISSN	1387-7003
DOI	https://doi.org/10.1016/j.inoche.2005.07.014
Status	Udgivet - okt. 2005

Emneord

Alkyl radicals
Alkylcobalt(III)
NMR
Pentaamminecobalt(III)

Adgang til dokumentet

10.1016/j.inoche.2005.07.014

http://www.mendeley.com/research/alkylcobaltiii-compounds-ammine-ligands

Citationsformater

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title = "Alkylcobalt(III) compounds with ammine ligands",

abstract = "Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.",

keywords = "Alkyl radicals, Alkylcobalt(III), NMR, Pentaamminecobalt(III)",

author = "Pauli Kofod",

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doi = "10.1016/j.inoche.2005.07.014",

language = "English",

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T1 - Alkylcobalt(III) compounds with ammine ligands

AU - Kofod, Pauli

PY - 2005/10

Y1 - 2005/10

N2 - Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

AB - Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

KW - Alkyl radicals

KW - Alkylcobalt(III)

KW - NMR

KW - Pentaamminecobalt(III)

U2 - 10.1016/j.inoche.2005.07.014

DO - 10.1016/j.inoche.2005.07.014

M3 - Journal article

SN - 1387-7003

VL - 8

SP - 943

EP - 946

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -