Alkylcobalt(III) compounds with ammine ligands

Pauli Kofod

doi:10.1016/j.inoche.2005.07.014

Alkylcobalt(III) compounds with ammine ligands

Pauli Kofod

Ernæring og Sundhedsuddannelsen - Slagelse

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

Original language	English
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	10
Pages (from-to)	943-946
Number of pages	4
ISSN	1387-7003
DOIs	https://doi.org/10.1016/j.inoche.2005.07.014
Publication status	Published - Oct 2005

Access to Document

10.1016/j.inoche.2005.07.014

http://www.mendeley.com/research/alkylcobaltiii-compounds-ammine-ligands

Cite this

@article{39e9a8a414374d10b6e16ead595c5531,

title = "Alkylcobalt(III) compounds with ammine ligands",

abstract = "Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.",

keywords = "Alkyl radicals, Alkylcobalt(III), NMR, Pentaamminecobalt(III)",

author = "Pauli Kofod",

year = "2005",

month = oct,

doi = "10.1016/j.inoche.2005.07.014",

language = "English",

volume = "8",

pages = "943--946",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "10",

}

TY - JOUR

T1 - Alkylcobalt(III) compounds with ammine ligands

AU - Kofod, Pauli

PY - 2005/10

Y1 - 2005/10

N2 - Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

AB - Amminecobalt(III) compounds with a coordinated primary alkyl group (ethyl, n-propyl, n-butyl, 2-phenylethyl, 3-aminopropyl) have been prepared using monoalkylhydrazines as alkylating agents. The identities have been established using solution 1H and 13C NMR spectroscopy and elemental analysis. The pentaammine(alkyl)cobalt(III) cations decompose in neutral aqueous solution to give alkyl radicals. ?? 2005 Elsevier B.V. All rights reserved.

KW - Alkyl radicals

KW - Alkylcobalt(III)

KW - NMR

KW - Pentaamminecobalt(III)

U2 - 10.1016/j.inoche.2005.07.014

DO - 10.1016/j.inoche.2005.07.014

M3 - Journal article

SN - 1387-7003

VL - 8

SP - 943

EP - 946

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -