The Co III—C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate

Pernille Harris; Pauli Kofod; Yong Sheng Song; Erik Larsen

doi:10.1107/S0108270102022825

The Co III—C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate

Pernille Harris
, Pauli Kofod
, Yong Sheng Song
, Erik Larsen

Ernæring og Sundhedsuddannelsen - Slagelse

University College of Nothern Denmark

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

In the title compound, [Co(C6H15N3)(C7H15N2S)]S2O6·H2O, the Co-C bond distance is 1.9930 (13) Å, which is shorter than for related compounds with the linear 1,6-diamino-3-thiahexan-4-ide anion in place of the macrocyclic 1-thia-4,7-diazacyclodecan-8-ide anion. The coordinated carbanion produces an elongation of 0.102 (7) Å of the Co-N bond to the 1,4,7-triazacyclononane N atom in the trans position. This relatively small trans influence is presumably a result of the triamine ligand forming strong bonds to the CoIII atom.

Original language	English
Journal	Acta Crystallographica. Section C: Crystal Structure Communications
Volume	59
Issue number	2
Pages (from-to)	m58-m60
Number of pages	3
ISSN	0108-2701
DOIs	https://doi.org/10.1107/S0108270102022825
Publication status	Published - 15 Feb 2003

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@article{74a2809174bb494d9028c4bd2668d2e8,

title = "The Co III{\textemdash}C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate",

abstract = "In the title compound, [Co(C6H15N3)(C7H15N2S)]S2O6·H2O, the Co-C bond distance is 1.9930 (13) {\AA}, which is shorter than for related compounds with the linear 1,6-diamino-3-thiahexan-4-ide anion in place of the macrocyclic 1-thia-4,7-diazacyclodecan-8-ide anion. The coordinated carbanion produces an elongation of 0.102 (7) {\AA} of the Co-N bond to the 1,4,7-triazacyclononane N atom in the trans position. This relatively small trans influence is presumably a result of the triamine ligand forming strong bonds to the CoIII atom.",

author = "Pernille Harris and Pauli Kofod and Song, \{Yong Sheng\} and Erik Larsen",

year = "2003",

month = feb,

day = "15",

doi = "10.1107/S0108270102022825",

language = "English",

volume = "59",

pages = "m58--m60",

journal = "Acta Crystallographica. Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

}

The Co III—C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate. / Harris, Pernille; Kofod, Pauli; Song, Yong Sheng et al.
In: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 59, No. 2, 15.02.2003, p. m58-m60.

Research output: Contribution to journal › Journal article › Research › peer-review

TY - JOUR

T1 - The Co III—C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate

AU - Harris, Pernille

AU - Kofod, Pauli

AU - Song, Yong Sheng

AU - Larsen, Erik

PY - 2003/2/15

Y1 - 2003/2/15

N2 - In the title compound, [Co(C6H15N3)(C7H15N2S)]S2O6·H2O, the Co-C bond distance is 1.9930 (13) Å, which is shorter than for related compounds with the linear 1,6-diamino-3-thiahexan-4-ide anion in place of the macrocyclic 1-thia-4,7-diazacyclodecan-8-ide anion. The coordinated carbanion produces an elongation of 0.102 (7) Å of the Co-N bond to the 1,4,7-triazacyclononane N atom in the trans position. This relatively small trans influence is presumably a result of the triamine ligand forming strong bonds to the CoIII atom.

AB - In the title compound, [Co(C6H15N3)(C7H15N2S)]S2O6·H2O, the Co-C bond distance is 1.9930 (13) Å, which is shorter than for related compounds with the linear 1,6-diamino-3-thiahexan-4-ide anion in place of the macrocyclic 1-thia-4,7-diazacyclodecan-8-ide anion. The coordinated carbanion produces an elongation of 0.102 (7) Å of the Co-N bond to the 1,4,7-triazacyclononane N atom in the trans position. This relatively small trans influence is presumably a result of the triamine ligand forming strong bonds to the CoIII atom.

U2 - 10.1107/S0108270102022825

DO - 10.1107/S0108270102022825

M3 - Journal article

SN - 0108-2701

VL - 59

SP - m58-m60

JO - Acta Crystallographica. Section C: Crystal Structure Communications

JF - Acta Crystallographica. Section C: Crystal Structure Communications

IS - 2

ER -

The Co III—C bond in (1-thia-4,7-diazacyclodecyl-κ3N4, N7, C10)(1,4,7-triazacyclononane-κ3N1, N4, N7)cobalt(III) dithionate hydrate

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